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Thermal shock occurs when a thermal gradient causes different parts of an object to expand by different amounts. This differential expansion can be understood in terms of stress or of strain, equivalently. At some point, this stress can exceed the strength of the material, causing a crack to form. If nothing stops this crack from propagating through the material, it will cause the object's structure to fail.

Failure due to thermal shock can be prevented by;

  1. Reducing the thermal gradient seen by the object, by
    1. changing its temperature more slowly
    2. increasing the material's thermal conductivity
  2. Reducing the material's coefficient of thermal expansion
  3. Increasing its strength
  4. Introducing built-in compressive stress, as for example in tempered glass
  5. Decreasing its Young's modulus
  6. Increasing its toughness, by
    1. crack tip blunting, i.e., plasticity or phase transformation
    2. crack deflection

Contents

Effect on materials [edit]

Borosilicate glass is made to withstand thermal shock better than most other glass through a combination of reduced expansion coefficient and greater strength, though fused quartz outperforms it in both these respects. Some glass-ceramic materials (mostly in LAS system[1]) include a controlled proportion of material with a negative expansion coefficient, so that the overall coefficient can be reduced to almost exactly zero over a reasonably wide range of temperatures.

Reinforced carbon-carbon is extremely resistant to thermal shock, due to graphite's extremely high thermal conductivity and low expansion coefficient, the high strength of carbon fiber, and a reasonable ability to deflect cracks within the structure.

To measure thermal shock the impulse excitation technique proved to be a useful tool. It can be used to measure Young's modulus, Shear modulus, Poisson's ratio and damping coefficient in a non destructive way. The same test-piece can be measured after different thermal shock cycles and this way the deterioration in physical properties can be mapped out.

Relative robustness of materials [edit]

The robustness of a material to thermal shock, or thermal shock resistance [2]

T. J. Lu, N. A. Fleck, The Thermal Shock Resistance of Solids, United Kingdom, http://www-mech.eng.cam.ac.uk/profiles/fleck/papers/96.pdf</ref>, is characterized with the thermal shock parameter:[3]

R_{\mathrm{T}} = \frac{k\sigma_{\mathrm{T}}(1-\nu)}{\alpha E}\,,

where

Thermal shock parameter in the physics of solid-state lasers [edit]

The laser gain medium generates heat. This heat is drained through the heat sink. The transfer of heat occurs at a certain temperature gradient. The non-uniform thermal expansion of a bulk material causes the stress and tension, which may break the device even at a slow change of temperature. (for example, continuous-wave operation). This phenomenon is also called thermal shock. The robustness of a laser material to the thermal shock is characterized by the thermal shock parameter. [3] (see above)

Roughly, at the efficient operation of laser, the power P_{\mathrm{h}} of heat generated in the gain medium is proportional to the output power P_{\mathrm{s}} of the laser, and the coefficient q of proportionality can be interpreted as heat generation parameter; then, P_{\mathrm{h}}=q P_{\mathrm{s}}. The heat generation parameter is basically determined by the quantum defect of the laser action, and one can estimate q=1-\omega_{\mathrm{s}}/\omega_{\mathrm{p}}, where \omega_{\mathrm{p}} and \omega_{\mathrm{s}} are frequency of the pump and that of the lasing.

Then, for the layer of the gain medium placed at the heat sink, the maximal power can be estimated as

P_{\mathrm{s, max}} = 3 \frac{R_{\mathrm{T}}}{q} \frac{L^2}{h},\,

where h is thickness of the layer and L is the transversal size. This estimate assumes the unilateral heat drain, as it takes place in the active mirrors. For the double-side sink, the coefficient 4 should be applied.

Thermal loading [edit]

The estimate above is not the only parameter which determines the limit of overheating of a gain medium. The maximal raise \Delta T of temperature, at which the medium still can efficiently lase, is also important property of the laser material. This overheating limits the maximal power with estimate

P_{\mathrm{s, max}} = 2 \frac {k \Delta T}{q} \frac{L^2}{h}\,

Combination of the two estimates above of the maximal power gives the estimate

P_{\mathrm{s, max}} = R \frac{L^2}{h}\,

where


R= \textrm{min}
\left\{
\begin{array}{c}
  3 R_{\mathrm{T}}/q\\
  2 k\Delta T/q
\end{array}
\right.
Estimates [4] of maximal value of loss \beta, at which desirable output power P is still available in a single disk laser, versus normalized power s=\frac{\omega_{\rm p}}{\omega_{\rm s}}\frac{P Q}{R^2}, and experimental data (circles)

is thermal loading; parameter, which is important property of the laser material. The thermal loading, saturation intensity Q and the loss \beta determine the limit of power scaling of the disk lasers .[5] Roughly, the maximal power at the optimised sizes L and h, is of order of P=\frac{R^2}{Q\beta^3}. This estimate is very sensitive to the loss \beta. However, the same expression can be interpreted as a robust estimate of the upper bound of the loss ~\beta~ required for the desirable output power P:

~\beta_{\mathrm{max}}=\left(\frac{R^2}{PQ}\right)^{\frac{1}{3}}.

All the disk lasers reported work at the round-trip loss below this estimate.[4] The thermal shock parameter and the loading depend of the temperature of the heat sink. Certain hopes are related with a laser, operating at cryogenic temperatures. The corresponding Increase of the thermal shock parameter would allow to softer requirements for the round-trip loss of the disk laser at the power scaling.

Examples of thermal shock failure [edit]

  • Hard rocks containing ore veins such as quartzite were formerly broken down using fire-setting, which involved heating the rock face with a wood fire, then quenching with water to induce crack growth. It is described by Diodorus Siculus in Egyptian gold mines, Pliny the Elder and Georg Agricola.
  • Ice cubes placed in a glass of warm water crack by thermal shock as the exterior surface increases in temperature much faster than the interior. As ice has a larger volume than the water that created it, the outer layer shrinks as it warms and begins to melt, whilst the interior remains largely unchanged. This rapid change in volume between different layers creates stresses in the ice that build until the force exceeds the strength of the ice, and a crack forms, sometimes with enough force to shoot ice shards out of the container.
  • Incandescent bulbs that have been running for a while have a very hot surface. Splashing cold water on them can cause the glass to shatter due to thermal shock, and the bulb to implode.
  • An antique cast iron cookstove is basically an iron box on legs, that has a cast iron top. One builds a wood or coal fire inside the box and cooks on the top outer surface of the box, like a griddle. If one builds too hot a fire, and then tries to cool the stove by pouring water on the top surface, it will crack and perhaps fail by thermal shock.
  • The causes of three aircraft incidents in the 1990s (United Airlines Flight 585, USAir Flight 427 and Eastwind Airlines Flight 517). Thermal shock caused their power control unit in the tail to jam and cause rudder hardover, forcing the planes in the direction the rudder turns.
  • It is widely hypothesized[by whom?] that following the casting of the Liberty Bell, it was allowed to cool too quickly which weakened the integrity of the bell and resulted in a large crack along the side of it the first time it was rung. Similarly, the strong gradient of temperature (due to the fire) is believed to cause the crash of the Tsar Bell.
  • Thermal shock is a primary contributor to head gasket failure in internal combustion engines.

See also [edit]

References [edit]

  1. ^ Scott L. Swartz, Ceramics having negative coefficient of thermal expansion, method of making such ceramics, and parts made from such ceramics, United States Patent 6066585
  2. ^ T. J. Lue; N. A. Fleck (1998). "The Thermal Shock Resistance of Solids". Acta Materialia 46 (13): 4755–4768. 
  3. ^ a b W.F.Krupke; M.D. Shinn, J.E. Marion, J.A. Caird, and S.E. Stokowski (1986). "Spectroscopic, optical, and thermomechanical properties of neodymium- and chromium-doped gadolinium scandium gallium garnet" (abstract). JOSAB 3 (1): 102–114. Bibcode:1986JOSAB...3..102K. doi:10.1364/JOSAB.3.000102. 
  4. ^ a b D.Kouznetsov; J.-F.Bisson (2008). "Role of the undoped cap in the scaling of a thin disk laser". JOSA B 25 (3): 338–345. Bibcode:2008JOSAB..25..338K. doi:10.1364/JOSAB.25.000338. 
  5. ^ D. Kouznetsov; J.F. Bisson, J. Dong, and K. Ueda (2006). "Surface loss limit of the power scaling of a thin-disk laser" (abstract). JOSAB 23 (6): 1074–1082. Bibcode:2006JOSAB..23.1074K. doi:10.1364/JOSAB.23.001074. Retrieved 2007-01-26. ; [1]

Original courtesy of Wikipedia: http://en.wikipedia.org/wiki/Thermal_shock — Please support Wikipedia.
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FoodProductionDaily.com

FoodProductionDaily.com
Wed, 15 May 2013 23:54:29 -0700

The combination of thermal shock and wash down water pressure can causes cracks and leaks in the metal detector aperture liner. This can result in water intrusion and a disturbance of the metal detecting coils causing instability or faults, said the firm.

Toronto Star

Toronto Star
Thu, 16 May 2013 21:01:44 -0700

It can, however, become subject to thermal shock and subsequently flake if exposed to a hot pan. Limestone: Impact and heat resistant, this warm stone is only available in a few tones but comes in a variety of fossil patterns with some more decorated ...
 
Plastics Today
Thu, 16 May 2013 11:40:29 -0700

With the LCD TV bezels the combination of thermal shock and the compression of the sintered cavities normally associated with molding, the life span of this particular technology is around 20,000 closures before the inserts start to crack. Sintered ...
 
4-traders (press release)
Tue, 14 May 2013 01:33:33 -0700

The optimized design and assembly technology of the new automotive qualified EconoDUAL™ 3 modules enables a more than three times higher thermal cycling capability, while the thermal shock capability is increased by a factor of ten compared to the ...

New Zealand Herald

New Zealand Herald
Sat, 11 May 2013 10:34:42 -0700

The shark looked otherwise healthy and he did not know how she died, but it may have been from thermal shock caused by cold water, Duffy said. Oceanic whitetip sharks were once common in equatorial waters, but had been hit hard by the shark finning ...

WXIA-TV

WXIA-TV
Wed, 08 May 2013 20:00:50 -0700

The company said several events can lead to glass breaking, including "thermal shock, sudden contact with hard surfaces, improper care or usage, etc., and this breakage may occur sometime after the causal event." Jarden said it would reach out to ...

ElectronicsWeekly.com

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Thu, 09 May 2013 06:10:02 -0700

“We have put through standard thermal cycling and thermal shock IPC tests and its maintains its peel-strength and electrical isolation,” said Curtis. “With anodising you will see cracks after thermal cycling. This ceramic does not experience this ...
 
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Wed, 15 May 2013 00:09:10 -0700

Chimney Liner Installation: Many homes have a terra cotta flue tile liner. While these liners are very effective as heat insulators they are also very brittle and usually crack when they are exposed to thermal shock. Chimney Cap Installation: A chimney ...
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